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This article is cited in 2 scientific papers (total in 2 papers)
Plasma Investigations
Nonmonotonous distribution of population of the $a^3\Sigma^+_g$ triplet state rotational levels in corona discharge in cryogenic helium gas
N. Bonifacia, V. M. Atrazhevb, V. A. Shakhatovc, R. E. Boltnev, K. von Haeftend, J. Elorantae a University of Grenoble 1 — Joseph Fourier
b Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
c A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
d University of Leicester
e Department of Chemistry and Biochemistry, University of Northridge, USA
Abstract:
We observed the spectra within the wavelength range of $910$–$990$ nm of emission of the corona discharge in supercritical helium gas at $6$–$11$ K. This spectral range contains the molecular bands of the $\rm He^*_2$ excimer radiative transitions $(c^3\Sigma^+_g \to a^3\Sigma^+_u)$ between the electron-vibrational-rotational levels of the $c^3\Sigma^+_g$ and the $a^3\Sigma^+_u$ triplet states. We have determined the populations of the rotational levels (quantity of molecules in the given excited state among the excited molecules of the discharge) of the $c^3\Sigma^+_g$ excited state from experimental values of the intensity of the respective electron-vibrational-rotational lines. The calculated population distribution is nonmonotonous. The population of the level with the rotation quantum number $K' = 18$ (the level number) is higher than those of the levels with the other $K'$ values.
Received: 08.10.2015 Accepted: 13.10.2015
Citation:
N. Bonifaci, V. M. Atrazhev, V. A. Shakhatov, R. E. Boltnev, K. von Haeften, J. Eloranta, “Nonmonotonous distribution of population of the $a^3\Sigma^+_g$ triplet state rotational levels in corona discharge in cryogenic helium gas”, TVT, 55:3 (2017), 337–344; High Temperature, 55:3 (2017), 326–333
Linking options:
https://www.mathnet.ru/eng/tvt8749 https://www.mathnet.ru/eng/tvt/v55/i3/p337
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