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Teplofizika vysokikh temperatur, 2010, Volume 48, Issue 4, Pages 504–511 (Mi tvt762)  

This article is cited in 6 scientific papers (total in 6 papers)

Thermophysical Properties of Materials

Combined equation of state for liquids and gases, which includes the classical and scaling parts

P. P. Bezverkhiiab, V. G. Martynetsb, E. V. Matizenb

a Novosibirsk State University
b Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
Full-text PDF (716 kB) Citations (6)
Abstract: A new equation of state is suggested, which describes the $P$$\rho$$T$ data for $^4$He and SF$_6$ in the ranges of reduced densities $-1 < (\rho;-\rho_c)/\rho_c < 1$ and of reduced temperatures $-0.3 < (T-T_c)/T_c < 0.3$ ($\rho_c$ and $T_c$ are the critical values). This equation includes the regular equation of state approximating the $P$$\rho$$T$ data outside of the critical region and the nonparametric scaling equation of state adequately describing the $P$$\rho$$T$ data in the vicinity of the critical points, which are combined by the crossover function. The classical function of damping of fluctuations of density and temperature when moving away from the critical point is suggested as the crossover function. Two equations of state are used for the regular part of combined equation, namely, the new cubic equation of state suggested by us and the equation of state of Kaplun and Meshalkin. The nonparametric scaling equation of state with three system-dependent constants is used as the scaling part of the combined equation. The conditions $(\partial P/\partial v)_T= 0$ and $(\partial^2 P/\partial v^2)_T = 0$ are valid for the combined equation at the critical point; binodal and spinodal are present, as is the case in classical equations of state. The approximation of the most exact data on $^4$He and SF$_6$ using the new equation reveals that the latter equation correctly describes the $P$$\rho$$T$ data with mean-square error with respect to pressure of $\pm 0.5\ \%$.
Received: 04.03.2009
English version:
High Temperature, 2010, Volume 48, Issue 4, Pages 482–488
DOI: https://doi.org/10.1134/S0018151X10040048
Bibliographic databases:
Document Type: Article
UDC: 536.44:536.63:536.71
Language: Russian
Citation: P. P. Bezverkhii, V. G. Martynets, E. V. Matizen, “Combined equation of state for liquids and gases, which includes the classical and scaling parts”, TVT, 48:4 (2010), 504–511; High Temperature, 48:4 (2010), 482–488
Citation in format AMSBIB
\Bibitem{BezMarMat10}
\by P.~P.~Bezverkhii, V.~G.~Martynets, E.~V.~Matizen
\paper Combined equation of state for liquids and gases, which includes the classical and scaling parts
\jour TVT
\yr 2010
\vol 48
\issue 4
\pages 504--511
\mathnet{http://mi.mathnet.ru/tvt762}
\transl
\jour High Temperature
\yr 2010
\vol 48
\issue 4
\pages 482--488
\crossref{https://doi.org/10.1134/S0018151X10040048}
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\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-77955718753}
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  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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