|
Teplofizika vysokikh temperatur, 2013, Volume 51, Issue 1, Pages 79–85
(Mi tvt59)
|
|
|
|
This article is cited in 23 scientific papers (total in 23 papers)
Thermophysical Properties of Materials
Asymptotic properties of ideal curves on a thermodynamic surface
V. I. Nedostup Physico-Chemical Institute, National Academy of Science of Ukraine, Odessa, Ukraine
Abstract:
The configurations and properties of the characteristic curves on the thermodynamic surface of a real gas, that is, of locus points where the configuration component of a thermodynamic property becomes zero, have been analyzed. The relation of asymptotic properties of the curves with a virial equation of state at $\rho\to0$ and with a hypothetical fluid system overcooled to $0$ K at $T\to0$ has been studied. The correlation of asymptotic properties of the curves manifesting themselves, in particular, in the direct relationship of coordinates of characteristic points of ideal curves on a thermodynamic surface with an intermolecular interaction potential has been demonstrated.
Received: 13.12.2011
Citation:
V. I. Nedostup, “Asymptotic properties of ideal curves on a thermodynamic surface”, TVT, 51:1 (2013), 79–85; High Temperature, 51:1 (2013), 72–78
Linking options:
https://www.mathnet.ru/eng/tvt59 https://www.mathnet.ru/eng/tvt/v51/i1/p79
|
|