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Teplofizika vysokikh temperatur, 2003, Volume 41, Issue 5, Pages 706–713
(Mi tvt1707)
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This article is cited in 1 scientific paper (total in 1 paper)
Thermophysical Properties of Materials
The activity of the components of a $\mathrm{Na}$–$\mathrm{K}$–$\mathrm{Cs}$ system at high temperatures
É. É. Shpil'rain, S. N. Skovorod'ko, A. G. Mozgovoi Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
Abstract:
The activity coefficients of the components of a $\mathrm{Na}$–$\mathrm{K}$–$\mathrm{Cs}$ ternary system in a temperature range of $773$–$1200$ K are determined using the previously calculated thermodynamic properties, in particular, the activity of the components of binary alloys of alkali metals such as $\mathrm{Na}$–$\mathrm{K}$, $\mathrm{Na}$–$\mathrm{Cs}$, and $\mathrm{K}$–$\mathrm{Cs}$, at high temperatures [1–3]. The sides of the triangle of the phase diagram of this system are constituted by the binary $\mathrm{Na}$–$\mathrm{K}$, $\mathrm{Na}$–$\mathrm{Cs}$, and $\mathrm{K}$–$\mathrm{Cs}$ binary alloys. The results obtained are used to calculate the saturated vapor pressure of the sodium–potassium-cesium eutectic ($22.1$ wt $\%\mathrm{K}$ and $73.8$ wt $\%\mathrm{Cs}$ [4, 5]) in the same temperature range. The calculated data are in good agreement with the recommended reference data [6].
Received: 13.01.2003
Citation:
É. É. Shpil'rain, S. N. Skovorod'ko, A. G. Mozgovoi, “The activity of the components of a $\mathrm{Na}$–$\mathrm{K}$–$\mathrm{Cs}$ system at high temperatures”, TVT, 41:5 (2003), 706–713; High Temperature, 41:5 (2003), 619–626
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https://www.mathnet.ru/eng/tvt1707 https://www.mathnet.ru/eng/tvt/v41/i5/p706
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