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Teplofizika vysokikh temperatur, 2004, Volume 42, Issue 6, Pages 878–884
(Mi tvt1604)
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This article is cited in 3 scientific papers (total in 3 papers)
Thermophysical Properties of Materials
Interaction potentials of nine quasi-spherical molecules in the database on the transport properties of gases
L. R. Fokina, L. Zarkovab, M. Damyanovab a Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Institute of Electronics, Bulgarian Academy of Sciences, Sofia,
Bulgaria
Abstract:
Experimental data on the second virial coefficient and viscosity are generalized using ($m-6$) Lennard-Jones potentials with four and three parameters for a group of rarefied gases consisting of quasi-spherical molecules with tetra- and octahedral symmetry. Analysis is made of correlations of the parameters of potentials with the structural characteristics of molecules and critical temperatures of substances. The parameters of three-parameter ($m-6$) Lennard–Jones potential for nine molecules of $\mathrm{CH}_4$, $\mathrm{CF}_4$, $\mathrm{CCl}_4$, $\mathrm{C}(\mathrm{CH}_3)_4$, $\mathrm{SiCl}_4$, $\mathrm{Si}(\mathrm{CH}_3)_4$, $\mathrm{SF}_6$, $\mathrm{MoF}_6$, and $\mathrm{WF}_6$ are included in the EPIDIF information-and-computation database (epitaxy and diffusion processes) on the transport properties of rarefied gases and gas mixtures.
Received: 17.03.2004
Citation:
L. R. Fokin, L. Zarkova, M. Damyanova, “Interaction potentials of nine quasi-spherical molecules in the database on the transport properties of gases”, TVT, 42:6 (2004), 878–884; High Temperature, 42:6 (2004), 888–894
Linking options:
https://www.mathnet.ru/eng/tvt1604 https://www.mathnet.ru/eng/tvt/v42/i6/p878
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