|
Teplofizika vysokikh temperatur, 2005, Volume 43, Issue 5, Pages 727–731
(Mi tvt1421)
|
|
|
|
This article is cited in 1 scientific paper (total in 1 paper)
Thermophysical Properties of Materials
The Heat Capacity and Thermodynamic Functions of Ternary Manganites $\text{DyM}^{\text{I}}\text{MgMn}_2\text{O}_6$ $(\text{M}^{\text{I}}$ - $\text{Na}$, $\text{K}$, $\text{Cs})$ in the Temperature Range from $223$ to $673$ K
B. K. Kasenov, Zh. N. Akisheva, E. S. Mustafin, Sh. B. Kasenova, Zh. I. Sagintaeva, Zh. S. Bekturganov, M. A. Akubaeva Institute for Phytochemistry, Ministry of Education and Science, Republic of Kazakhstan, Karaganda
Abstract:
The solid-phase method is used to synthesize ternary manganites of composition $\text{DyM}^{\text{I}}\text{MgMn}_2\text{O}_6$ $(\text{M}^{\text{I}}$ - $\text{Na}$, $\text{K}$, $\text{Cs})$; their X-ray investigation is performed to demonstrate that they all crystallize in orthorhombic system. Their heat capacity is determined experimentally in the range from $223$ to $673$ K, equations are derived which describe the dependences $C^{\circ}_p \sim f(T)$, and the thermodynamic functions $C^{\circ}_p(T)$, $H^{\circ}(T) - H^{\circ}(298.15)$, $S^{\circ}(T)$, and $\Phi^{**}(T)$ are calculated. Second-order phase transitions are observed in the process of investigation of heat capacity.
Received: 02.09.2004
Citation:
B. K. Kasenov, Zh. N. Akisheva, E. S. Mustafin, Sh. B. Kasenova, Zh. I. Sagintaeva, Zh. S. Bekturganov, M. A. Akubaeva, “The Heat Capacity and Thermodynamic Functions of Ternary Manganites $\text{DyM}^{\text{I}}\text{MgMn}_2\text{O}_6$ $(\text{M}^{\text{I}}$ - $\text{Na}$, $\text{K}$, $\text{Cs})$ in the Temperature Range from $223$ to $673$ K”, TVT, 43:5 (2005), 727–731; High Temperature, 43:5 (2005), 727–732
Linking options:
https://www.mathnet.ru/eng/tvt1421 https://www.mathnet.ru/eng/tvt/v43/i5/p727
|
|