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Teplofizika vysokikh temperatur, 2022, Volume 60, Issue 1, Pages 46–50
DOI: https://doi.org/10.31857/S0040364422010215
(Mi tvt11519)
 

Thermophysical Properties of Materials

Thermodynamics of the evaporation of scandium trifluoride and the composition of its vapor

E. L. Osinaa, S. B. Osinb

a Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Lomonosov Moscow State University, Faculty of Chemistry
References:
Abstract: Based on the critical analysis of the experimental and theoretical data on the structure and vibrational frequencies of dimeric scandium trifluoride, the molecular constant values of the $\rm Sc_2\rm F_6$ compound are chosen and its thermodynamic functions are calculated. The scandium trifluoride vapor composition is calculated in the temperature range of $1200$ to $1825$ K. The enthalpies of sublimation and formation of the scandium trifluoride monomer and dimer are determined according to the third law of thermodynamics. The values obtained are added to the IVTANTHERMO software package database.
Received: 24.12.2020
Revised: 31.05.2021
Accepted: 28.09.2021
English version:
High Temperature, 2022, Volume 60, Issue 1, Pages 41–44
DOI: https://doi.org/10.1134/S0018151X22010151
Bibliographic databases:
Document Type: Article
UDC: 544.31.031:546.881.5
Language: Russian
Citation: E. L. Osina, S. B. Osin, “Thermodynamics of the evaporation of scandium trifluoride and the composition of its vapor”, TVT, 60:1 (2022), 46–50; High Temperature, 60:1 (2022), 41–44
Citation in format AMSBIB
\Bibitem{OsiOsi22}
\by E.~L.~Osina, S.~B.~Osin
\paper Thermodynamics of the evaporation of scandium trifluoride and the composition of its vapor
\jour TVT
\yr 2022
\vol 60
\issue 1
\pages 46--50
\mathnet{http://mi.mathnet.ru/tvt11519}
\crossref{https://doi.org/10.31857/S0040364422010215}
\elib{https://elibrary.ru/item.asp?id=48506027}
\transl
\jour High Temperature
\yr 2022
\vol 60
\issue 1
\pages 41--44
\crossref{https://doi.org/10.1134/S0018151X22010151}
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