Abstract:
The article presents a brief review of works on the refinement of the Zr–C phase diagram: the parameters of the solidus and liquidus lines, the temperature and composition of congruently melting carbide, and the ZrC–C eutectic temperature. We consider the experimental data on the heat of fusion and the specific heat of liquid ZrCx obtained by electrical-pulse heating (previously presented only in graphical form). The Cp(T) curve is numerically processed, and an equation is presented that approximates the temperature dependence of the specific heat of liquid zirconium carbide ZrCx([C]/[Zr]=0.95) from the melting point at 3840 K to 5000 K.
Citation:
N. M. Aristova, S. V. Onufriev, A. I. Savvatimskii, “Specific heat of liquid zirconium carbide ZrC0.95 at temperatures up to 5000 K”, TVT, 58:5 (2020), 749–757; High Temperature, 58:5 (2020), 681–688
\Bibitem{AriOnuSav20}
\by N.~M.~Aristova, S.~V.~Onufriev, A.~I.~Savvatimskii
\paper Specific heat of liquid zirconium carbide $\rm ZrC_{0.95}$ at temperatures up to $5000$~K
\jour TVT
\yr 2020
\vol 58
\issue 5
\pages 749--757
\mathnet{http://mi.mathnet.ru/tvt11364}
\crossref{https://doi.org/10.31857/S0040364420050014}
\elib{https://elibrary.ru/item.asp?id=43962079}
\transl
\jour High Temperature
\yr 2020
\vol 58
\issue 5
\pages 681--688
\crossref{https://doi.org/10.1134/S0018151X20050016}
\isi{https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Publons&SrcAuth=Publons_CEL&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=000601547100002}
\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85098002973}
Linking options:
https://www.mathnet.ru/eng/tvt11364
https://www.mathnet.ru/eng/tvt/v58/i5/p749
This publication is cited in the following 3 articles:
N. M. Aristova, G. V. Belov, “Thermodynamic properties of ZrC0.95−0.99 zirconium carbide in a condensed state”, High Temperature, 60:1 (2022), 19–27
A. I. Savvatimskiy, S. V. Onufriev, N. M. Aristova, “Physical properties of refractory carbides of metals of groups IV and V of the Mendeleev periodic table during rapid heating by an electric current pulse”, Phys. Usp., 65:6 (2022), 597–616
S. N. Grigoriev, Kh. Hamdy, M. A. Volosova, A. A. Okunkova, S. V. Fedorov, “Electrical discharge machining of oxide and nitride ceramics: a review”, Mater. Des., 209 (2021), 109965