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Teplofizika vysokikh temperatur, 2018, Volume 56, Issue 6, Pages 882–890
DOI: https://doi.org/10.31857/S004036440003565-5
(Mi tvt10934)
 

This article is cited in 1 scientific paper (total in 1 paper)

Thermophysical Properties of Materials

Modeling of multiphase thermodynamic equilibria of $\rm NaCl$$\rm H_2\rm O$ binary mixture in a wide range of pressures and temperatures

A. A. Afanasyev

Lomonosov Moscow State University, Institute of Mechanics
Full-text PDF (984 kB) Citations (1)
References:
Abstract: A method is proposed for the determination of the multiphase thermodynamic equilibria of a binary $\rm NaCl$$\rm H_2\rm O$ mixture over a wide range of pressures and temperatures, including the critical thermodynamic conditions and the $\rm NaCl$ melting point. The method is based on calculation of the thermodynamic potential of the mixture which is entropy as a function of pressure, enthalpy, and $\rm NaCl$ concentration. The potential is calculated from two mutually consistent equations of state. The first equation of state of the van der Waals type describes the parameters of the vapor and liquid phases and the supercritical fluid. The second, simpler, equation describes the parameters of the solid phase of the salt. The chemical potentials of the equations are consistent for the calculation of single-phase, two-phase, and three-phase equilibria of the vapor–liquid–solid phase type. The phase diagrams of the mixture in the pressure–enthalpy–composition and pressure–temperature–composition variables are constructed.
Funding agency Grant number
Russian Science Foundation 16-17-10199
This study was supported by the Russian Science Foundation, project no. 16-17-10199.
Received: 26.09.2017
Accepted: 26.12.2017
English version:
High Temperature, 2018, Volume 56, Issue 6, Pages 859–866
DOI: https://doi.org/10.1134/S0018151X18060019
Bibliographic databases:
Document Type: Article
UDC: 536.71:532.546
Language: Russian
Citation: A. A. Afanasyev, “Modeling of multiphase thermodynamic equilibria of $\rm NaCl$$\rm H_2\rm O$ binary mixture in a wide range of pressures and temperatures”, TVT, 56:6 (2018), 882–890; High Temperature, 56:6 (2018), 859–866
Citation in format AMSBIB
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\paper Modeling of multiphase thermodynamic equilibria of $\rm NaCl$--$\rm H_2\rm O$ binary mixture in a wide range of pressures and temperatures
\jour TVT
\yr 2018
\vol 56
\issue 6
\pages 882--890
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\crossref{https://doi.org/10.31857/S004036440003565-5}
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\jour High Temperature
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  • This publication is cited in the following 1 articles:
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