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This article is cited in 16 scientific papers (total in 16 papers)
Two-fluid picture of supercritical phenomena
V. P. Maslov Higher School of Economics, Moscow, Russia
Abstract:
We consider a parastatistics that does not distinguish objectively different objects but describes clusters in the supercritical state and determines the relation between the mesoscopic physics of clusters and the macroscopic thermodynamics of supercritical isotherms. We construct the supercritical picture of isochores and isotherms under the condition that the Boyle temperature, the Boyle density, and the critical point are known, and we justify the two-fluid model of supercritical thermodynamics mathematically. For the "cluster sponge," this leads to new relations different from the relations of the known Gentile statistics. We calculate the Frenkel temperature of the transition from rigid liquid to soft liquid.
Keywords:
parastatistics, van der Waals equation, mesoscopic physics, contour,
critical temperature, isochore, isotherm, Bachinskii condition, Zeno line,
Boyle temperature, Boyle density, Frenkel temperature.
Received: 18.02.2014
Citation:
V. P. Maslov, “Two-fluid picture of supercritical phenomena”, TMF, 180:3 (2014), 394–432; Theoret. and Math. Phys., 180:3 (2014), 1096–1129
Linking options:
https://www.mathnet.ru/eng/tmf8658https://doi.org/10.4213/tmf8658 https://www.mathnet.ru/eng/tmf/v180/i3/p394
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Abstract page: | 672 | Full-text PDF : | 226 | References: | 95 | First page: | 49 |
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