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Teoreticheskaya i Matematicheskaya Fizika, 1986, Volume 66, Number 2, Pages 290–301
(Mi tmf4624)
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This article is cited in 1 scientific paper (total in 1 paper)
Thermodynamics and anomalous slowing down of molecular structure relaxation in a flat channel
E. V. Kholopov
Abstract:
A simple model of spherical molecules in a flat channel manifests in transparent terms
of packing all the main features of the thermodynamics and kinetics of one-dimensional
systems unstable with respect to the occurrence of a superperiod. The phonon spectrum
and the vibrational contribution to the low-temperature thermodynamics associated with
the presence of domain walls are calculated. The relaxation of the domain wall density
is calculated for arbitrary initial deviation from the equilibrium value. An exponential
slowing down of the relaxation with decreasing temperature is predicted. The high-temperature
thermodynamics is calculated and extrapolation of the obtained results to low temperatures demonstrates the process of appearance of the superperiod.
Received: 25.12.1984
Citation:
E. V. Kholopov, “Thermodynamics and anomalous slowing down of molecular structure relaxation in a flat channel”, TMF, 66:2 (1986), 290–301; Theoret. and Math. Phys., 66:2 (1986), 191–199
Linking options:
https://www.mathnet.ru/eng/tmf4624 https://www.mathnet.ru/eng/tmf/v66/i2/p290
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Abstract page: | 321 | Full-text PDF : | 95 | References: | 55 | First page: | 1 |
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