Abstract:
For the system of classical particles interacting by pair short-range forces the explicitly convergent expansions on usual and complementary density and the contour integral representations are constructed for the all-round compression modulus, the modulus being sufficient to describe all the thermodynamic properties and being tentatively single-valued in the vicinity of the phase transition point. With the help of those the analytic representations of the equation of state as well as specific configuration integral are found. The elaborated technique is approved on the exactly solved model – the theory of the Van der Waals substance being a model “substance” for which the Van der Waals equation is the exact
equation of state.
Citation:
I. I. Ivanchik, “Analytic representation for the equation of state in classical statistical mechanics”, TMF, 108:1 (1996), 135–158; Theoret. and Math. Phys., 108:1 (1996), 958–976
\Bibitem{Iva96}
\by I.~I.~Ivanchik
\paper Analytic representation for the equation of state in classical statistical mechanics
\jour TMF
\yr 1996
\vol 108
\issue 1
\pages 135--158
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\crossref{https://doi.org/10.4213/tmf1183}
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\transl
\jour Theoret. and Math. Phys.
\yr 1996
\vol 108
\issue 1
\pages 958--976
\crossref{https://doi.org/10.1007/BF02070522}
\isi{https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Publons&SrcAuth=Publons_CEL&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=A1996WZ85900011}
Linking options:
https://www.mathnet.ru/eng/tmf1183
https://doi.org/10.4213/tmf1183
https://www.mathnet.ru/eng/tmf/v108/i1/p135
This publication is cited in the following 5 articles:
V. V. Ryazanov, “Equation of state and size distribution of particles in the Gibbs system”, High Temperature, 61:2 (2023), 185–199
V. V. Ryazanov, “Obtaining the thermodynamic relations for the Gibbs ensemble using the maximum entropy method”, Theoret. and Math. Phys., 194:3 (2018), 390–403
Georgiy I. Kalmykov, “Frame classification of the reduced labeled blocks”, Discrete Math. Appl., 26:1 (2016), 1–11
G. I. Kalmykov, “A Representation of Virial Coefficients That Avoids the Asymptotic Catastrophe”, Theoret. and Math. Phys., 130:3 (2002), 432–447
G. I. Kalmykov, “Mayer-series asymptotic catastrophe in classical statistical mechanics”, Theoret. and Math. Phys., 119:3 (1999), 778–795