|
This article is cited in 51 scientific papers (total in 51 papers)
Elemental phosphorus–strong base as a system for the synthesis of organophosphorus compounds
B. A. Trofimov, T. N. Rakhmatulina, N. K. Gusarova, S. F. Malysheva Irkutsk Institute of Chemistry, Siberian Branch of the USSR Academy of Sciences
Abstract:
A systematic review is presented on the reactions of elemental phosphorus with organic compounds in the presence of base, proceeding via polyphosphide and polyphosphinite anions. Particular attention has been paid to new effective methods of activating red phosphorus by superbase complexes, formed from alkali metal hydroxides and polar, non-hydroxylic solvents (HMPA, DMSO, DMF, triethylphosphine oxide), by the sodium/liquid ammonia system, or under phase transfer catalysis. The direct phosphorylation of organic halides, activated alkenes, acetylenes and oxiranes is also discussed. The bibliography includes 92 references.
Citation:
B. A. Trofimov, T. N. Rakhmatulina, N. K. Gusarova, S. F. Malysheva, “Elemental phosphorus–strong base as a system for the synthesis of organophosphorus compounds”, Usp. Khim., 60:12 (1991), 2619–2632; Russian Chem. Reviews, 60:12 (1991), 1360–1367
Linking options:
https://www.mathnet.ru/eng/rcr993https://doi.org/10.1070/RC1991v060n12ABEH001152 https://www.mathnet.ru/eng/rcr/v60/i12/p2619
|
Statistics & downloads: |
Abstract page: | 199 |
|