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This article is cited in 17 scientific papers (total in 17 papers)
Specific features of the chemical structure of the oxo-complexes of d0 and d2 metals with monodentate and polydentate ligands
M. A. Porai-Koshits, V. S. Sergienko Kurnakov Institute of General and Inorganic Chemistry of the USSR Academy of Sciences, Moscow
Abstract:
The structure of the oxo-complexes of transition d0 and d2 Group V–VII metals is discussed. Two types of distortion isomerism are considered: the trans-influence isomerism (the lengthening of the M=O multiple bond on passing from one isomer to another is accompanied by a shortening of the M–Ltrans bond) and the multiple bond isomerism (the lengthening of the M=O bond is not accompanied by a shortening of the M–Ltrans bond). The choice of the trans-partner out of the set of competing functional groups for the d0 metal is determined by the self-consistency principle, while for the d2 metal the rule becomes more complex and the choice of the trans-partner of the oxo-ligand depends on the individual features of the trans-ligand (on the combination of its σ- and π-donor properties). It is shown in relation to the d0-MoO2 and d2-ReO complexes with isotypical chelate O, N-donor ligands that the latter are coordinated to the metal in different ways. The bibliography includes 58 references.
Citation:
M. A. Porai-Koshits, V. S. Sergienko, “Specific features of the chemical structure of the oxo-complexes of d0 and d2 metals with monodentate and polydentate ligands”, Usp. Khim., 59:1 (1990), 86–105; Russian Chem. Reviews, 59:1 (1990), 52–62
Linking options:
https://www.mathnet.ru/eng/rcr787https://doi.org/10.1070/RC1990v059n01ABEH003509 https://www.mathnet.ru/eng/rcr/v59/i1/p86
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