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This article is cited in 208 scientific papers (total in 208 papers)
Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision
V. P. Ananikovab, L. L. Khemchyana, Yu. V. Ivanovaa, V. I. Bukhtiyarovcd, A. M. Sorokinc, I. P. Prosvirinc, S. Z. Vatsadzee, A. V. Medved'koe, V. N. Nurieve, A. D. Dilmana, V. V. Levina, I. V. Koptyugfd, K. V. Kovtunovfd, V. V. Zhivonitkofd, V. A. Likholobovg, A. V. Romanenkoc, P. A. Simonovcd, V. G. Nenajdenkoeh, O. I. Shmatovae, V. M. Muzalevskiye, M. S. Nechaevei, A. F. Asachenkoi, O. S. Morozovi, P. B. Dzhevakovi, S. N. Osipovh, D. V. Vorobyevah, M. A. Topchiyh, M. A. Zotovah, S. A. Ponomarenkoej, O. V. Borshchevj, Yu. N. Luponosovj, A. A. Rempelkl, A. A. Valeevakl, A. Yu. Stakheeva, O. V. Turovaa, I. S. Mashkovskya, S. V. Sysolyatinm, V. V. Malykhinm, G. A. Bukhtiyarovac, A. O. Terent'eva, I. B. Krylova a N.D. Zelinskii Institute of Organic Chemistry
b Saint Petersburg State University
c Boreskov Institute of Catalysis SB RAS, Novosibirsk
d Novosibirsk State University
e M. V. Lomonosov Moscow State University, Department of Chemistry
f International Tomography Center of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk
g Institute of Hydrocarbons Processing of SB RAS
h A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
i A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
j N. S. Enikolopov Institute of Synthetic Polymer Materials RAS, Moscow
k Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
l Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
m Institute for Problems of Chemical and Energetic Technology, Siberian Branch of the Russian Academy of Sciences, Biisk, Altai krai
Abstract:
The challenges of the modern society and the growing demand of high-technology sectors of industrial production bring about a new phase in the development of organic synthesis. A cutting edge of modern synthetic methods is introduction of functional groups and more complex structural units into organic molecules with unprecedented control over the course of chemical transformation. Analysis of the state-of-the-art achievements in selective organic synthesis indicates the appearance of a new trend — the synthesis of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity. Most advanced approaches to organic synthesis anticipated in the near future can be defined as “atomic precision” in chemical reactions. The present review considers selective methods of organic synthesis suitable for transformation of complex functionalized molecules under mild conditions. Selected key trends in the modern organic synthesis are considered including the preparation of organofluorine compounds, catalytic cross-coupling and oxidative cross-coupling reactions, atom-economic addition reactions, methathesis processes, oxidation and reduction reactions, synthesis of heterocyclic compounds, design of new homogeneous and heterogeneous catalytic systems, application of photocatalysis, scaling up synthetic procedures to industrial level and development of new approaches to investigation of mechanisms of catalytic reactions.
The bibliography includes 840 references.
Received: 30.05.2014
Citation:
V. P. Ananikov, L. L. Khemchyan, Yu. V. Ivanova, V. I. Bukhtiyarov, A. M. Sorokin, I. P. Prosvirin, S. Z. Vatsadze, A. V. Medved'ko, V. N. Nuriev, A. D. Dilman, V. V. Levin, I. V. Koptyug, K. V. Kovtunov, V. V. Zhivonitko, V. A. Likholobov, A. V. Romanenko, P. A. Simonov, V. G. Nenajdenko, O. I. Shmatova, V. M. Muzalevskiy, M. S. Nechaev, A. F. Asachenko, O. S. Morozov, P. B. Dzhevakov, S. N. Osipov, D. V. Vorobyeva, M. A. Topchiy, M. A. Zotova, S. A. Ponomarenko, O. V. Borshchev, Yu. N. Luponosov, A. A. Rempel, A. A. Valeeva, A. Yu. Stakheev, O. V. Turova, I. S. Mashkovsky, S. V. Sysolyatin, V. V. Malykhin, G. A. Bukhtiyarova, A. O. Terent'ev, I. B. Krylov, “Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision”, Usp. Khim., 83:10 (2014), 885–985; Russian Chem. Reviews, 83:10 (2014), 885–985
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https://www.mathnet.ru/eng/rcr716https://doi.org/10.1070/RC2014v83n10ABEH004471 https://www.mathnet.ru/eng/rcr/v83/i10/p885
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