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This article is cited in 39 scientific papers (total in 39 papers)
Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes
A. A. Nikolin, V. V. Negrebetsky Russian National Research Medical University named after N. I. Pirogov
Abstract:
The state of the art of the chemistry of hypercoordinate silicon compounds is analyzed. Published data on the current top-priority approaches to the preparative synthesis of these compounds and on their properties, structures and reactivity are summarized and generalized. Relying on the results obtained by modern physicochemical methods, the possible mechanisms of stereodynamic processes occurring in the coordination units of hypercoordinate silicon complexes are discussed. The bibliography includes 157 references.
Received: 21.03.2013
Citation:
A. A. Nikolin, V. V. Negrebetsky, “Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes”, Usp. Khim., 83:9 (2014), 848–883; Russian Chem. Reviews, 83:9 (2014), 848–883
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https://www.mathnet.ru/eng/rcr714https://doi.org/10.1070/RC2014v083n09ABEH004385 https://www.mathnet.ru/eng/rcr/v83/i9/p848
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