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This article is cited in 130 scientific papers (total in 130 papers)
Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components
O. G. Ellerta, M. V. Tsodikovb, S. A. Nikolaevc, V. M. Novotortseva a Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
b A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
c M. V. Lomonosov Moscow State University, Department of Chemistry
Abstract:
The review is concerned with correlations between synergetic effects and structural organization of the surface of bimetallic alloys that are used as active components of catalysts for selective hydrogenation of organic compounds and the oxidation of CO in hydrogen-rich mixtures. Studies on the preparation of novel highly efficient catalysts using modern theoretical approaches, computer-assisted molecular design and original synthetic procedures are considered. It is shown that introduction of a second metal into the monometallic catalyst and subsequent formation of an alloy with the modified structure of the surface and near-surface layers leads to nonadditive enhancement of catalytic activity and/or selectivity. Bibliography — 203 references.
Received: 22.10.2013
Citation:
O. G. Ellert, M. V. Tsodikov, S. A. Nikolaev, V. M. Novotortsev, “Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components”, Usp. Khim., 83:8 (2014), 718–732; Russian Chem. Reviews, 83:8 (2014), 718–732
Linking options:
https://www.mathnet.ru/eng/rcr709https://doi.org/10.1070/RC2014v083n08ABEH004432 https://www.mathnet.ru/eng/rcr/v83/i8/p718
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