|
This article is cited in 29 scientific papers (total in 29 papers)
Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions
O. D. Linnikov Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences
Abstract:
The models of formation of salt precipitates during crystallization from supersaturated aqueous solutions are analyzed. The results of theoretical simulations and experimental studies are compared. The attention is focused on the processes of crystal aggregation and agglomeration. The data on the mechanism of crystal intergrowth under conditions of mass crystallization of salts from supersaturated aqueous solutions are considered. The intergrowth process is shown to be described most reliably by the model based on the Polak theory according to which in supersaturated solutions, connecting nucleus-bridges are formed within aggregates between the closest faces of neighbouring crystals. The bibliography includes 159 references.
Received: 15.04.2013
Citation:
O. D. Linnikov, “Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions”, Usp. Khim., 83:4 (2014), 343–364; Russian Chem. Reviews, 83:4 (2014), 343–364
Linking options:
https://www.mathnet.ru/eng/rcr694https://doi.org/10.1070/RC2014v083n04ABEH004399 https://www.mathnet.ru/eng/rcr/v83/i4/p343
|
Statistics & downloads: |
Abstract page: | 245 |
|