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This article is cited in 142 scientific papers (total in 142 papers)
Non-classical structures of organic compounds: unusual stereochemistry and hypercoordination
V. I. Minkina, R. M. Minyaeva, R. Hoffmannb a Institute of Physical and Organic Chemistry at Southern Federal University
b Department of Chemistry and Chemical Biology, Cornell University
Abstract:
Non-classical structures of organic compounds are defined as molecules containing non-tetrahedral tetracoordinate and/or hypercoordinate carbon atoms. The evolution of the views on this subject is considered and the accumulated theoretical and experimental data on the structures and dynamic transformations of non-classical organic compounds are systematised. It is shown that computational analysis using the methods and the software potential of modern quantum chemistry has now acquired high predictive capacity and is the most important source of data on the structures of non-classical compounds. The bibliography includes 227 references.
Received: 15.05.2002
Citation:
V. I. Minkin, R. M. Minyaev, R. Hoffmann, “Non-classical structures of organic compounds: unusual stereochemistry and hypercoordination”, Usp. Khim., 71:11 (2002), 989–1014; Russian Chem. Reviews, 71:11 (2002), 869–892
Linking options:
https://www.mathnet.ru/eng/rcr592https://doi.org/10.1070/RC2002v071n11ABEH000729 https://www.mathnet.ru/eng/rcr/v71/i11/p989
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