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Russian Chemical Reviews, 2024, Volume 93, Issue 11, RCR5140
DOI: https://doi.org/10.59761/RCR5140
 

Unsaturated organosilanes: synthesis, transformations and applications

M. Yu. Moskalik, B. A. Shainyan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Abstract: The urgency of improving the efficiency of known methods and developing new ones for the synthesis of unsaturated silanes is caused by the need to obtain useful compounds, including biologically active ones, on their basis. This review considers methods for the preparation of unsaturated silanes, their transformations and prospects for their use as precursors in organic and organoelement synthesis. A large number of substituted organosilicon products are given, including those capable of further functionalization and the formation of heterocycles, including silaheterocycles.
The bibliography includes 205 references.
Keywords: alkynes; dienes; allenes; enynes; hydrosilylation; vinyl silanes, allyl silanes; silaheterocycles; vinylation; desilylation; cyclization; β-effect of silicon atom.
Received: 20.06.2024
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Document Type: Article
Language: English
Original paper language: Russian


Citation: M. Yu. Moskalik, B. A. Shainyan, “Unsaturated organosilanes: synthesis, transformations and applications”, Usp. Khim., 93:11 (2024), RCR5140; Russian Chem. Reviews, 93:11 (2024), RCR5140
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