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Russian Chemical Reviews, 2022, Volume 91, Issue 3, RCR5021
DOI: https://doi.org/10.1070/RCR5021 		 
This article is cited in 11 scientific papers (total in 11 papers)

Catalytic oligomerization and polymerization of ethylene with complexes of iron triad metals: influence of metal nature and new prospects

S. V. Zubkevicha, V. A. Tuskaevab, S. Ch. Gagievaa, B. M. Bulycheva

a Lomonosov Moscow State University, Faculty of Chemistry
b A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
English full-text Citations (11)
DOI: https://doi.org/10.1070/RCR5021
Abstract: In the last five years the field of catalytic oligomerization and polymerization of olefins using complexes of late transition metals has been the most intensively developing area of post-metallocene catalysis. This review is devoted to detailed analysis of the influence of metal nature on the catalytic properties of systems based on complexes of iron triad metals. Some novel and developing areas of application of such complexes in olefin oligomerization and polymerization (ethylene trimerization, production of olefins with an odd number of carbon atoms and polyethylene waxes, targeted synthesis of heavy fractions of ethylene oligomers) are surveyed. Different approaches to the heterogenization of catalysts on various solid supports are considered.
The bibliography includes 225 references.
Keywords: Nickel, cobalt, iron, ethylene, polymerization, oligomerization, post-metallocene catalysts, trimerization, metathesis, base oil, immobilization, polyethylene, wax.
Funding agency Grant number
Russian Foundation for Basic Research 20-13-50074
Ministry of Education and Science of the Russian Federation АААА-А16-116053110012-5
Russian Science Foundation 18-13-00375
The reported study was funded by Russian Foundation for Basic Research (Project No. 20-13-50074), by the Ministry of Science and Higher Education of the Russian Federation (Project No. AAAA-A16-116053110012-5) and by Russian Science Foundation (Project No. 18-13-00375)
Received: 29.03.2021
Russian version:
Uspekhi Khimii, 2022, Volume 91, Issue 3, RCR5021
DOI: https://doi.org/10.1070/RCR5021
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: S. V. Zubkevich, V. A. Tuskaev, S. Ch. Gagieva, B. M. Bulychev, “Catalytic oligomerization and polymerization of ethylene with complexes of iron triad metals: influence of metal nature and new prospects”, Usp. Khim., 91:3 (2022), RCR5021; Russian Chem. Reviews, 91:3 (2022), RCR5021
Citation in format AMSBIB
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\paper Catalytic oligomerization and polymerization of ethylene with complexes of iron triad metals: influence of metal nature and new prospects
\jour Usp. Khim.
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