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Russian Chemical Reviews, 2022, Volume 91, Issue 2, RCR5025
DOI: https://doi.org/10.1070/RCR5025 		 
This article is cited in 56 scientific papers (total in 56 papers)

Conjugated nitroxides

E. V. Tretyakova, V. I. Ovcharenkob, A. O. Terent'eva, I. B. Krylova, T. V. Magdesievac, D. G. Mazhukind, N. P. Gritsane

a N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
b International Tomography Center of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk
c Lomonosov Moscow State University, Faculty of Chemistry
d N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistryof the Siberian Branch of Russian Academy of Sciences
e Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Science
English full-text Citations (56)
DOI: https://doi.org/10.1070/RCR5025
Abstract: In recent years, research dealing with organic paramagnetic compounds such as stable radicals and high-spin systems has been focused on applied aspects. Several key trends have formed in the application and, hence, in the function-oriented synthesis of organic radicals and polyradicals. This review addresses one of such trends in which the dominant role is played by so-called conjugated nitroxides. Their specific feature is the presence of any unsaturated moiety (C=C, C=N or C=O multiple bond; aromatic or heteroaromatic ring; fused polyaromatic system) adjacent to the nitroxide group. The achievements of the chemistry of conjugated nitroxides are presented, and their physicochemical properties, magneto-structural correlations and practical applications are discussed.
The bibliography includes 641 references.
Keywords: organic paramagnets, nitroxide radicals, hybrid phenoxyl-nitroxides, unpaired electron delocalization, electrochemistry, high-spin systems, molecular magnetism, quantum-chemical calculations, parameters of the Hamiltonian spin, theoretical prediction of magnetic motives, structure-property correlations.
Funding agency Grant number
Russian Foundation for Basic Research 20-13-50016
Received: 13.05.2021
Russian version:
Uspekhi Khimii, 2022, Volume 91, Issue 2, RCR5025
DOI: https://doi.org/10.1070/RCR5025
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: E. V. Tretyakov, V. I. Ovcharenko, A. O. Terent'ev, I. B. Krylov, T. V. Magdesieva, D. G. Mazhukin, N. P. Gritsan, “Conjugated nitroxides”, Usp. Khim., 91:2 (2022), RCR5025; Russian Chem. Reviews, 91:2 (2022), RCR5025
Citation in format AMSBIB
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