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Russian Chemical Reviews, 2021, Volume 90, Issue 5, Pages 601–626
DOI: https://doi.org/10.1070/RCR4967 (Mi rcr4345) 		 
This article is cited in 10 scientific papers (total in 10 papers)

Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides

A. A. Valeevaab, A. A. Rempelabc, S. V. Rempel'ab, S. I. Sadovnikova, A. I. Guseva

a Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
c Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Yekaterinburg
English full-text Citations (10)
DOI: https://doi.org/10.1070/RCR4967
Abstract: The results of recent experimental studies of the influence of the size of oxide, carbide and sulfide nanoparticles on changes in their nonstoichiometry are analyzed and generalized. In relation to intrinsically nonstoichiometric titanium oxides and niobium and vanadium carbides, on the one hand, and stoichiometric silver sulfides, on the other hand, it is shown that a decrease in the particle size to the nano scale has a strong impact on the chemical composition of nanocrystalline compounds, viz., it leads to the occurrence of or to increase in nonstoichiometry. A conclusion is drawn that interplay between the particle size and nonstoichiometry is common to all solid nanocrystalline substances and should be taken into account in studies on the synthesis, structure and properties of these systems.
The bibliography includes 260 references.
Keywords: nonstoichiometry, nanocrystalline compounds, oxides, carbides, sulfides, size of nanoparticles.
Funding agency Grant number
Russian Science Foundation 14-23-00025
Ministry of Education and Science of the Russian Federation 0397-2019-0001
Received: 05.06.2020
Russian version:
Uspekhi Khimii, 2021, Volume 90, Issue 5, Pages 601–626
DOI: https://doi.org/10.1070/RCR4967
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: A. A. Valeeva, A. A. Rempel, S. V. Rempel', S. I. Sadovnikov, A. I. Gusev, “Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides”, Usp. Khim., 90:5 (2021), 601–626; Russian Chem. Reviews, 90:5 (2021), 601–626
Citation in format AMSBIB
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\paper Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides
\jour Usp. Khim.
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\issue 5
\pages 601--626
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\crossref{https://doi.org/10.1070/RCR4967}
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\jour Russian Chem. Reviews
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\vol 90
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\pages 601--626
\crossref{https://doi.org/10.1070/RCR4967}
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    • This publication is cited in the following 10 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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