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Russian Chemical Reviews, 2021, Volume 90, Issue 5, Pages 529–565
DOI: https://doi.org/10.1070/RCR4992 (Mi rcr4343) 		 
This article is cited in 25 scientific papers (total in 25 papers)

Alkyl complexes of divalent lanthanides and heavy alkaline earth metals

D. O. Khristolyubova, D. M. Lyubova, A. A. Trifonovab

a G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod
b A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
English full-text Citations (25)
DOI: https://doi.org/10.1070/RCR4992
Abstract: The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The synthetic aspects and structural features of this unique class of organometallic compounds, which contain highly reactive M–C bonds, including alkyl, $\alpha$-silylmethyl, and also benzyl, diphenylmethyl, and triphenylmethyl derivatives are considered.
The bibliography includes 157 references.
Keywords: divalent lanthanides, alkaline earth metals, alkyl complexes, synthesis, structure, reactivity, catalytic activity.
Funding agency Grant number
Russian Foundation for Basic Research 19-13-50411
Received: 14.08.2020
Russian version:
Uspekhi Khimii, 2021, Volume 90, Issue 5, Pages 529–565
DOI: https://doi.org/10.1070/RCR4992
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: D. O. Khristolyubov, D. M. Lyubov, A. A. Trifonov, “Alkyl complexes of divalent lanthanides and heavy alkaline earth metals”, Usp. Khim., 90:5 (2021), 529–565; Russian Chem. Reviews, 90:5 (2021), 529–565
Citation in format AMSBIB
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\paper Alkyl complexes of divalent lanthanides and heavy alkaline earth metals
\jour Usp. Khim.
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\issue 5
\pages 529--565
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    • This publication is cited in the following 25 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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