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Russian Chemical Reviews, 2021, Volume 90, Issue 5, Pages 529–565
DOI: https://doi.org/10.1070/RCR4992
(Mi rcr4343)
 

This article is cited in 30 scientific papers (total in 30 papers)

Alkyl complexes of divalent lanthanides and heavy alkaline earth metals

D. O. Khristolyubova, D. M. Lyubova, A. A. Trifonovab

a G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod
b A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
Abstract: The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The synthetic aspects and structural features of this unique class of organometallic compounds, which contain highly reactive M–C bonds, including alkyl, $\alpha$-silylmethyl, and also benzyl, diphenylmethyl, and triphenylmethyl derivatives are considered.
The bibliography includes 157 references.
Keywords: divalent lanthanides, alkaline earth metals, alkyl complexes, synthesis, structure, reactivity, catalytic activity.
Funding agency Grant number
Russian Foundation for Basic Research 19-13-50411
Received: 14.08.2020
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: D. O. Khristolyubov, D. M. Lyubov, A. A. Trifonov, “Alkyl complexes of divalent lanthanides and heavy alkaline earth metals”, Russian Chem. Reviews, 90:5 (2021), 529–565
Citation in format AMSBIB
\Bibitem{KhrLyuTri21}
\by D.~O.~Khristolyubov, D.~M.~Lyubov, A.~A.~Trifonov
\paper Alkyl complexes of divalent lanthanides and heavy alkaline earth metals
\jour Russian Chem. Reviews
\yr 2021
\vol 90
\issue 5
\pages 529--565
\mathnet{http://mi.mathnet.ru/eng/rcr4343}
\crossref{https://doi.org/10.1070/RCR4992}
\adsnasa{https://adsabs.harvard.edu/cgi-bin/bib_query?2021RuCRv..90..529K}
\isi{https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Publons&SrcAuth=Publons_CEL&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=000655059900001}
\elib{https://elibrary.ru/item.asp?id=46792790}
\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85107123457}
Linking options:
  • https://www.mathnet.ru/eng/rcr4343
  • https://doi.org/10.1070/RCR4992
  • https://www.mathnet.ru/eng/rcr/v90/i5/p529
  • This publication is cited in the following 30 articles:
    1. M. A. Shmelev, A. A. Levina, A. S. Chistyakov, E. A. Varaksina, J. K. Voronina, G. A. Razgonyaeva, I. V. Taidakov, A. A. Sidorov, I. L. Eremenko, Mendeleev Commun., 35:1 (2025), 35–38  mathnet  crossref
    2. D. M. Lyubov, A. V. Cherkasov, A. A. Trifonov, Mendeleev Commun., 35:1 (2025), 31–34  mathnet  crossref
    3. Alexander N. Selikhov, Yulia V. Nelyubina, Rinat R. Aysin, Alexander A. Trifonov, Dalton Trans., 2025  crossref
    4. Krishna Atal, Sushama Kumari, Krishna Kumar Jhankal, Swati Bugalia, J Incl Phenom Macrocycl Chem, 2025  crossref
    5. Krishna Atal, Urmila Phageria, Sushama Kumari, Yogpal Dhayal, Swati Bugalia, Inorganica Chimica Acta, 561 (2024), 121857  crossref
    6. Dmitry M. Lyubov, Hamza Zakaria, Yulia V. Nelyubina, Rinat R. Aysin, Sergey S. Bukalov, Alexander A. Trifonov, Chemistry A European J, 30:12 (2024)  crossref
    7. Alexander N. Selikhov, Mikhail A. Bogachev, Yulia V. Nelyubina, Grigory Yu. Zhigulin, Sergey Yu. Ketkov, Alexander A. Trifonov, Inorg. Chem. Front., 11:14 (2024), 4336  crossref
    8. Xianghui Shi, Peng Deng, Thayalan Rajeshkumar, Laurent Maron, Jianhua Cheng, Chem. Sci., 2024  crossref
    9. A. N. Selikhov, G. R. Taranenko, Yu. V. Nelyubina, A. A. Trifonov, Russ J Coord Chem, 50:2 (2024), 96  crossref
    10. Simon Sengupta, Sven Krieck, Matthias Westerhausen, Dalton Trans., 53:36 (2024), 14961  crossref
    11. A. N. Selikhov, G. R. Taranenko, Yu. V. Nelyubina, A. A. Trifonov, Koordinacionnaâ himiâ, 50:3 (2024)  crossref
    12. A. N. Selikhov, Yu. V. Nelyubina, A. A. Trifonov, Russ Chem Bull, 73:10 (2024), 2844  crossref
    13. A. Mortis, C. Maichle-Mössmer, R. Anwander, Chemistry A European J., 29:23 (2023), e202203824  crossref
    14. S. Sengupta, Ph. Schüler, P. Liebing, M. Westerhausen, Chemistry A European J., 29:23 (2023), e202300035  crossref
    15. N. Yu. Rad'kova, A. V. Cherkasov, A. A. Trifonov, Russ J Coord Chem, 49:11 (2023), 710  crossref  crossref
    16. A. N. Selikhov, A. V. Cherkasov, Yu. V. Nelyubina, A. A. Trifonov, ACS Catal., 13:19 (2023), 12582  crossref
    17. Z. Shafi, J. K. Gibson, Inorg. Chem., 62:45 (2023), 18399  crossref
    18. P. Schüler, S. Sengupta, S. Krieck, M. Westerhausen, Chemistry A European J., 29:40 (2023)  crossref
    19. X. Shi, T. Rajeshkumar, L. Maron, J. Cheng, Chem. Commun., 58:9 (2022), 1362–1365  crossref  isi
    20. Yu. Denisenko, A. Sedykh, A. Oreshonkov, M. Molokeev, N. Azarapin, I. Sal'nikova, O. Chimitova, V. Andreev, I. Razumkova, K. Buschbaum, Eur. J. Inorg. Chem., 2022:12 (2022), e202200043  crossref  isi
    Citing articles in Google Scholar: Russian citations, English citations
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