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This article is cited in 23 scientific papers (total in 23 papers)
Alkyl complexes of divalent lanthanides and heavy alkaline earth metals
D. O. Khristolyubova, D. M. Lyubova, A. A. Trifonovab a G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod
b A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
Abstract:
The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The synthetic aspects and structural features of this unique class of organometallic compounds, which contain highly reactive M–C bonds, including alkyl, $\alpha$-silylmethyl, and also benzyl, diphenylmethyl, and triphenylmethyl derivatives are considered.
The bibliography includes 157 references.
Keywords:
divalent lanthanides, alkaline earth metals, alkyl complexes, synthesis, structure, reactivity, catalytic activity.
Received: 14.08.2020
Citation:
D. O. Khristolyubov, D. M. Lyubov, A. A. Trifonov, “Alkyl complexes of divalent lanthanides and heavy alkaline earth metals”, Usp. Khim., 90:5 (2021), 529–565; Russian Chem. Reviews, 90:5 (2021), 529–565
Linking options:
https://www.mathnet.ru/eng/rcr4343https://doi.org/10.1070/RCR4992 https://www.mathnet.ru/eng/rcr/v90/i5/p529
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