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Russian Chemical Reviews, 2021, Volume 90, Issue 2, Pages 199–230
DOI: https://doi.org/10.1070/RCR4982
(Mi rcr4331)
 

This article is cited in 11 scientific papers (total in 11 papers)

Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane

L. G. Menchikov, E. V. Shulishov, Yu. V. Tomilov

N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow
English full-text Citations (11)
Abstract: The main achievements and development trends of the past 107–15 years related to the catalytic cyclopropanation of unsaturated compounds with diazomethane are integrated and analyzed. The attention is focused on the most efficient catalysts based on palladium compounds. Data on the effects of substrate structure and nature of catalyst components on the regio- and stereoselectivity of these reactions are systematized. Characteristic features of safe methods for diazomethane generation are considered, including the use of membrane technologies and continuous-flow and in situ preparation methods, which have prospects for industrial application.
The bibliography includes 281 references.
Keywords: diazomethane, generation, cyclopropanation, unsaturated, compound, catalyst, palladium, iron-catalyzed.
Received: 20.07.2020
Russian version:
Uspekhi Khimii, 2021, Volume 90, Issue 2, Pages 199–230
DOI: https://doi.org/10.1070/RCR4982
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: L. G. Menchikov, E. V. Shulishov, Yu. V. Tomilov, “Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane”, Usp. Khim., 90:2 (2021), 199–230; Russian Chem. Reviews, 90:2 (2021), 199–230
Citation in format AMSBIB
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  • https://doi.org/10.1070/RCR4982
  • https://www.mathnet.ru/eng/rcr/v90/i2/p199
  • This publication is cited in the following 11 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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