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Russian Chemical Reviews, 2020, Volume 89, Issue 2, Pages 250–274
DOI: https://doi.org/10.1070/RCR4916
(Mi rcr4283)
 

This article is cited in 30 scientific papers (total in 30 papers)

Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I

I. P. Beletskayaa, C. Nájerab, M. Yusb

a Lomonosov Moscow State University, Faculty of Chemistry
b University of Alicante, Spain
English full-text Citations (30)
Abstract: The review presents state-of-the-art data on the influence of catalysts (mainly transition metal complexes) on the regioselectivity of a number of reactions. The most important addition reactions to unsaturated bonds are considered, in particular, hydroformylation, hydrosilylation, hydroboration and hydroxy-, alkoxy- and aminocarbonylation, which give predominantly one product. Particular attention is given to reactions with divergent regioselectivity. The reaction conditions, the structures of metal complexes and the ligands involved are indicated and, in some cases, the reaction mechanism is discussed. Examples of industrial processes using homogeneous catalysis are given.
The bibliography includes 203 references.
Funding agency Grant number
Russian Science Foundation 19-13-00223
Received: 02.08.2019
Russian version:
Uspekhi Khimii, 2020, Volume 89, Issue 2, Pages 250–274
DOI: https://doi.org/10.1070/RCR4916
Bibliographic databases:
Document Type: Article
Language: English
Original paper language: Russian
Citation: I. P. Beletskaya, C. Nájera, M. Yus, “Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I”, Usp. Khim., 89:2 (2020), 250–274; Russian Chem. Reviews, 89:2 (2020), 250–274
Citation in format AMSBIB
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\by I.~P.~Beletskaya, C.~N\'ajera, M.~Yus
\paper Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I
\jour Usp. Khim.
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\vol 89
\issue 2
\pages 250--274
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\adsnasa{https://adsabs.harvard.edu/cgi-bin/bib_query?2020RuCRv..89..250B}
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\pages 250--274
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  • https://doi.org/10.1070/RCR4916
  • https://www.mathnet.ru/eng/rcr/v89/i2/p250
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    This publication is cited in the following 30 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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