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This article is cited in 30 scientific papers (total in 30 papers)
Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I
I. P. Beletskayaa, C. Nájerab, M. Yusb a Lomonosov Moscow State University, Faculty of Chemistry
b University of Alicante, Spain
Abstract:
The review presents state-of-the-art data on the influence of catalysts (mainly transition metal complexes) on the regioselectivity of a number of reactions. The most important addition reactions to unsaturated bonds are considered, in particular, hydroformylation, hydrosilylation, hydroboration and hydroxy-, alkoxy- and aminocarbonylation, which give predominantly one product. Particular attention is given to reactions with divergent regioselectivity. The reaction conditions, the structures of metal complexes and the ligands involved are indicated and, in some cases, the reaction mechanism is discussed. Examples of industrial processes using homogeneous catalysis are given.
The bibliography includes 203 references.
Received: 02.08.2019
Citation:
I. P. Beletskaya, C. Nájera, M. Yus, “Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I”, Usp. Khim., 89:2 (2020), 250–274; Russian Chem. Reviews, 89:2 (2020), 250–274
Linking options:
https://www.mathnet.ru/eng/rcr4283https://doi.org/10.1070/RCR4916 https://www.mathnet.ru/eng/rcr/v89/i2/p250
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