Suprathermal particles in astrochemistry

The kinetic Monte Carlo method, used in astrochemistry to investigate suprathermal (hot) particles at the molecular level, is presented. Different modifications of this method, aimed at studying the influence of suprathermal particles in the processes occurring in gas and dust envelopes surrounding astrophysical objects – prestellar and protostellar cores of molecular clouds, planets, their moons, and comets in the Solar and extrasolar planetary systems – are considered. The important role of the fraction of suprathermal particles in astrochemical applications of this approach is demonstrated. The presence of these particles leads to local changes in the chemical composition; causes non-thermal emissions in gas and dust envelopes; enhances the chemical exchange between the gas and dust fractions of envelope; leads to the formation of extended hot coronae of planets; increases non-thermal atmospheric losses, thus determining the evolution of planetary atmosphere on astronomical time scales; and facilitates the formation of complex molecules in gas and dust envelopes of astrophysical objects.
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