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This article is cited in 19 scientific papers (total in 19 papers)
Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes
V. A. D'yakonov, G. N. Kadikova, U. M. Dzhemilev Institute of Petrochemistry and Catalysis of RAS, Ufa
Abstract:
The current review summarizes the published data on transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes. It addresses homodimerization of cycloheptatrienes and cyclocodimerization of the latter with alkenes, dienes and alkynes in the presence of transition metal complexes that occur via [2$\pi$+2$\pi$], [3$\pi$+2$\pi$], [6$\pi$+2$\pi$], [6$\pi$+4$\pi$] and [6$\pi$+2$\pi$+2$\pi$] cycloadditions. Special attention is given to the application of these reactions in the synthesis of valuable strained bi-, tri- and polycyclic compounds and for the development of methods of stereoselective synthesis of natural products. The bibliography includes 91 references.
Received: 26.10.2017
Citation:
V. A. D'yakonov, G. N. Kadikova, U. M. Dzhemilev, “Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes”, Usp. Khim., 87:8 (2018), 797–820; Russian Chem. Reviews, 87:8 (2018), 797–820
Linking options:
https://www.mathnet.ru/eng/rcr4222https://doi.org/10.1070/RCR4793 https://www.mathnet.ru/eng/rcr/v87/i8/p797
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