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This article is cited in 11 scientific papers (total in 11 papers)
Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids
T. V. Andrushkevich, Yu. A. Chesalov Boreskov Institute of Catalysis SB RAS, Novosibirsk
Abstract:
The results of studies on the mechanism of heterogeneous catalytic oxidation of organic compounds of different chemical structure to carboxylic acids are analyzed and generalized. The concept developed by Academician G. K. Boreskov, according to which the direction of the reaction is governed by the structure and bond energy of surface intermediates, was confirmed taking the title processes as examples. Quantitative criteria of the bond energies of surface compounds of oxidizable reactants, reaction products and oxygen that determine the selective course of the reaction are presented.
The bibliography includes 195 references.
Received: 22.08.2017
Citation:
T. V. Andrushkevich, Yu. A. Chesalov, “Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids”, Usp. Khim., 87:6 (2018), 586–603; Russian Chem. Reviews, 87:6 (2018), 586–603
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https://www.mathnet.ru/eng/rcr4213https://doi.org/10.1070/RCR4779 https://www.mathnet.ru/eng/rcr/v87/i6/p586
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