Abstract:
Ion-conducting solid metal oxides are widely used in high-temperature electrochemical devices for energy conversion and oxygen separation. However, liquid metal oxides possessing unique electrochemical properties still remain of limited use. The review demonstrates the potential for practical applications of molten oxides. The transport properties of molten oxide materials are discussed. The emphasis is placed on the chemical diffusion of oxygen in the molten oxide membrane materials for electrochemical energy conversion and oxygen separation. The thermodynamics of these materials is considered. The dynamic polymer chain model developed to describe the oxygen ion transport in molten oxides is discussed. Prospects for further research into molten oxide materials are outlined. The bibliography includes 145 references.
Citation:
V. V. Belousov, “Innovative oxide materials for electrochemical energy conversion and oxygen separation”, Russian Chem. Reviews, 86:10 (2017), 934–950
This publication is cited in the following 15 articles:
Valery V. Belousov, The Journal of Chemical Physics, 161:24 (2024)
Valery V. Belousov, Phys. Chem. Chem. Phys., 2023
V. V. Belousov, Doklady Rossiiskoi akademii nauk. Khimiya, nauki o materialakh, 510:1 (2023), 48
V. V. Belousov, Dokl Phys Chem, 510:1 (2023), 71
Jiayan Teng, Tian Xia, Liping Sun, Lihua Huo, Qiang Li, Hui Zhao, Journal of Alloys and Compounds, 929 (2022), 167311
V. V. Belousov, S. V. Fedorov, Phys. Chem. Chem. Phys., 23:41 (2021), 24029–24038
E. I. Knyazeva, A. I. Pylinina, I. I. Mikhalenko, Russ. J. Phys. Chem. A, 94:9 (2020), 1786–1790
V. P. Meshalkin, A. V. Belyakov, Processes, 8:8 (2020), 1004
V. V. Belousov, S. V. Fedorov, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 50:2 (2019), 857–865
V. V. Belousov, S. V. Fedorov, M. S. Sedov, J. Electrochem. Soc., 166:12 (2019), H573–H579
E. I. Knyazeva, A. I. Pylinina, I. I. Mikhalenko, Mendeleev Commun., 29:5 (2019), 541–543
V. V. Belousov, S. V. Fedorov, ACS Appl. Mater. Interfaces, 10:26 (2018), 21794–21798
I. V. Kulbakin, S. V. Fedorov, V. V. Belousov, J. Electrochem. Soc., 165:13 (2018), H861–H865
I. V. Kulbakin, A. A. Solovieva, S. V. Fedorov, V. V. Artemov, V. V. Belousov, Inorg. Mater., 54:10 (2018), 1055–1061
A. A. Solovieva, I. V. Kulbakin, Third International Youth Scientific Forum With International Participation New Materials, IOP Conference Series-Materials Science and Engineering, 347, IOP Publishing Ltd, 2018, UNSP 012036
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