Abstract:
The most important fields of coordination chemistry of fullerenes, including those dealing with synthesis and properties of η2η2 complexes, multinuclear complexes and coordination dimers, have been considered. In addition, our recent results have been presented concerning the synthesis of fullerene complexes with transition metals by the reduction method and through the reaction of transition-metal compounds with fullerene radical anion salts. The properties of coordination compounds with monomeric, dimeric and polymeric fullerenes as well as with fullerene anions are discussed.
The bibliography includes 103 references.
Keywords:
Fullerenes C<sub>60</sub> and C<sub>70</sub>, coordination compounds, transition metals, reduction, magnetic properties EPR spectroscopy, spectra in the IR- and UV-visible-near IR-ranges.
Citation:
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Pavel A. Sobov, Alexey V. Kuzmin, Salavat S. Khasanov, Alexander F. Shestakov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, Inorg. Chem., 62:43 (2023), 17736
Maxim A. Faraonov, Alexey V. Kuzmin, Salavat S. Khasanov, Alexander F. Shestakov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, Inorg. Chem., 61:49 (2022), 20144
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