Abstract:
The results of studies of alterations in the elemental and SARA compositions and physicochemical and rheological properties of highly viscous heavy crude oils upon catalytic and non-catalytic aquathermolysis are generalized. The chemistry of transformations of model hydrocarbons and heteroatomic compounds in aqueous media at high temperature, including subcritical and supercritical conditions, is considered. Comparative analysis of methods for activation of oil conversion via aquathermolysis using hydrogen donors, oil-soluble and water-soluble nanodispersed catalysts, ionic hydrogenation processes and various ways for reservoir heating is presented. Problems and prospects of oil-field implementation of catalytic aquathermolysis for upgrading heavy oils and natural bitumen are discussed.
The bibliography includes 234 references.
Received: 18.09.2014
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Document Type:
Article
Language: English
Original paper language: Russian
Citation:
B. P. Tumanyan, N. N. Petrukhina, G. P. Kayukova, D. K. Nurgaliev, L. E. Foss, G. V. Romanov, “Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation”, Russian Chem. Reviews, 84:11 (2015), 1145–1175
\Bibitem{TumPetKay15}
\by B.~P.~Tumanyan, N.~N.~Petrukhina, G.~P.~Kayukova, D.~K.~Nurgaliev, L.~E.~Foss, G.~V.~Romanov
\paper Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation
\jour Russian Chem. Reviews
\yr 2015
\vol 84
\issue 11
\pages 1145--1175
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\crossref{https://doi.org/10.1070/RCR4500}
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Linking options:
https://www.mathnet.ru/eng/rcr4078
https://doi.org/10.1070/RCR4500
https://www.mathnet.ru/eng/rcr/v84/i11/p1145
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