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This article is cited in 36 scientific papers (total in 36 papers)
$C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis
S. G. Zlotin, S. V. Kochetkov N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
Abstract:
The review is devoted to the application of $C_2$-symmetric diamines and their derivatives as organocatalysts for asymmetric reactions (aldol, Michael, Mannich, Diels–Alder reactions, desymmetrization, allylation, etc.). Amino acid derivatives, di- and polyamides (sulfamides), bisureas, bisthioureas, bisamidines and bisguanidines are considered. Significant attention is given to the effect of the catalyst structure on the mechanism of catalytic action. Successful applications of such catalysts in enantioselective synthesis of chiral biologically active compounds are summarized.
The bibliography includes 181 references.
Received: 23.03.2015
Citation:
S. G. Zlotin, S. V. Kochetkov, “$C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis”, Usp. Khim., 84:11 (2015), 1077–1099; Russian Chem. Reviews, 84:11 (2015), 1077–1099
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https://www.mathnet.ru/eng/rcr4075https://doi.org/10.1070/RCR4562 https://www.mathnet.ru/eng/rcr/v84/i11/p1077
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