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This article is cited in 30 scientific papers (total in 30 papers)
Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions
E. N. Ushakovab, S. P. Gromovb a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
b Photochemistry Centre, Russian Academy of Sciences, Moscow
Abstract:
This review deals with the methods of supramolecular chemistry used for controlling the efficiency and stereoselectivity of intermolecular [2+2] photocycloaddition of olefins and other unsaturated compounds in homogeneous solutions. The best-studied methods are self-assembly through cation–macrocycle interactions, complexation with molecular templates through hydrogen bonding, and confinement of the reactants in supramolecular containers. The possibilities of using anionic templates and combined supramolecular approaches are discussed.
The bibliography includes 107 references.
Received: 08.10.2014
Citation:
E. N. Ushakov, S. P. Gromov, “Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions”, Usp. Khim., 84:8 (2015), 787–802; Russian Chem. Reviews, 84:8 (2015), 787–802
Linking options:
https://www.mathnet.ru/eng/rcr4060https://doi.org/10.1070/RCR4514 https://www.mathnet.ru/eng/rcr/v84/i8/p787
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