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This article is cited in 23 scientific papers (total in 23 papers)
Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds
J. J. Medvedev, V. A. Nikolaev Institute of Chemistry, St. Petersburg State University
Abstract:
Multicomponent reactions of diazo compounds catalyzed by Rh$^\mathrm{II}$ complexes become a powerful tool for organic synthesis. They enable three- or four-step processes to be carried out as one-pot procedures (actually as one step) with high stereoselectivity to give complex organic molecules, including biologically active compounds. This review addresses recent results in the chemistry of Rh-catalyzed multicomponent reactions of diazocarbonyl compounds with the intermediate formation of N-, O- and C=O–ylides. The diastereo- and enantioselectivity of these reactions and the possibility of using various co-catalysts to increase the efficiency of the processes under consideration are discussed.
The bibliography includes 120 references.
Received: 07.11.2014
Citation:
J. J. Medvedev, V. A. Nikolaev, “Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds”, Usp. Khim., 84:7 (2015), 737–757; Russian Chem. Reviews, 84:7 (2015), 737–757
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https://www.mathnet.ru/eng/rcr4058https://doi.org/10.1070/RCR4522 https://www.mathnet.ru/eng/rcr/v84/i7/p737
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