Abstract:
The review summarizes published data on the methods of the synthesis of fused nitrogen-containing heterocycles via push-pull enamines (mainly enaminones). Both intermolecular (cyclocondensations) and intramolecular (cyclizations) transformations of enamines, in which both nucleophilic centres of enamine (carbon and nitrogen) are incorporated into the resulting heterocycle, are considered. The data on the reactivity of enamines cover a broad range of facile methods for the preparation of diverse fused pyridines (quinolines, isoquinolines, pyridopyridines, etc.) and pyrroles (indoles, tetrahydrocarbazoles, pyrrolopyridines, etc.).
The bibliography includes 191 references.
Received: 07.11.2014
Bibliographic databases:
Document Type:
Article
Language: English
Original paper language: Russian
Citation:
D. V. Dar'in, P. S. Lobanov, “Push-pull enamines in the synthesis of fused azaheterocycles”, Russian Chem. Reviews, 84:6 (2015), 601–633
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\by D.~V.~Dar'in, P.~S.~Lobanov
\paper Push-pull enamines in the synthesis of fused azaheterocycles
\jour Russian Chem. Reviews
\yr 2015
\vol 84
\issue 6
\pages 601--633
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\crossref{https://doi.org/10.1070/RCR4528}
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Linking options:
https://www.mathnet.ru/eng/rcr4052
https://doi.org/10.1070/RCR4528
https://www.mathnet.ru/eng/rcr/v84/i6/p601
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