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This article is cited in 2 scientific papers (total in 2 papers)
Adiabatic compression in studies on the kinetics and mechanism of reactions involving fluorine-containing carbenes
Yu. A. Kolbanovskii A. V. Topchiev Institute of Petrochemical Synthesis of the Academy of Sciences of the USSR, Moscow
Abstract:
The physicochemical principles of adiabatic compression and its characteristics and potentialities in studies on the kinetics and mechanism of thermal gas-phase reactions are examined. The results of studying reactions involving fluorine-containing carbenes are presented. Information is given on the high-temperature tautomerism of tetrafiuoroethylene–trifluoromethylfluorocarbene, which has been detected and studied using kinetic spectroscopy during adiabatic compression. The set of experimental data on the pyrolysis and gas-phase isomerisation of perfluoroolefins has been interpreted using the concept of tautomeric changes involving the 1,2-shift of a fluorine atom in olefins. The bibliography includes 53 references.
Citation:
Yu. A. Kolbanovskii, “Adiabatic compression in studies on the kinetics and mechanism of reactions involving fluorine-containing carbenes”, Usp. Khim., 58:11 (1989), 1800–1814; Russian Chem. Reviews, 58:11 (1989), 1024–1032
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https://www.mathnet.ru/eng/rcr4012https://doi.org/10.1070/RC1989v058n11ABEH003494 https://www.mathnet.ru/eng/rcr/v58/i11/p1800
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