|
This article is cited in 1 scientific paper (total in 1 paper)
Chemiluminescence in cryogenic matrices
S. V. Lotnik, V. P. Kazakov Institute of Chemistry of the Bashkir Scientific Center, Ural Branch of the USSR, Ufa
Abstract:
The literature data on chemiluminescence (CL) in cryogenic matrices have been classified and correlated for the first time. The role of studies on phosphorescence and CL at low temperatures in the development of cryochemistry is shown. The features of low-temperature CL in matrices of nitrogen and inert gases (fine structure of spectra, matrix effects) and the data on the mobility and reactivity of atoms and radicals at very low temperatures are examined. The trends in the development of studies on CL in cryogenic matrices, such as the search for systems involving polyatomic molecules and extending the forms of CL reactions, are followed. The reactions of active nitrogen with hydrocarbons that are accompanied by light emission and CL in the oxidation of carbenes at T ≥ 77 K are examined. The bibliography includes 112 references.
Citation:
S. V. Lotnik, V. P. Kazakov, “Chemiluminescence in cryogenic matrices”, Usp. Khim., 58:4 (1989), 566–590; Russian Chem. Reviews, 58:4 (1989), 337–351
Linking options:
https://www.mathnet.ru/eng/rcr3962https://doi.org/10.1070/RC1989v058n04ABEH003444 https://www.mathnet.ru/eng/rcr/v58/i4/p566
|
Statistics & downloads: |
Abstract page: | 76 |
|