|
This article is cited in 28 scientific papers (total in 28 papers)
Reactions of N-chloramines and N-haloamides with unsaturated compounds
A. N. Mirskova, T. I. Drozdova, G. G. Levkovskaya, M. G. Voronkov Irkutsk Institute of Chemistry, Siberian Branch of the USSR Academy of Sciences
Abstract:
The results obtained from studying the reactions of N-chloramines, N-halocarbamates, and N-haloamides of carboxylic, sulphonic, and phosphoric acids with unsaturated compounds have been correlated and classified. It is shown that the direction of addition of N-haloamines and N-haloamides to alkenes, dienes, alkenynes, and acetylenes, giving saturated adducts, is determined by the conditions of homolytic or heterolytic initiation. The reactions of N-chlorodialkylamines with olefins in the presence of sulphur trioxide are discussed. A new method of activating electrophilic reagents by introducing sulphur trioxide on to the N–Cl bond is identified. An essentially new trend is reported for the reactions of N,N-dihaloamides of sulphonic and carboxylic acids and also N,N-dihalocarbamates with polyhaloethylenes, giving acylimines of polyhaloaldehydes, which are highly reactive syntones for the synthesis of fine organic chemicals. The bibliography includes 216 references.
Citation:
A. N. Mirskova, T. I. Drozdova, G. G. Levkovskaya, M. G. Voronkov, “Reactions of N-chloramines and N-haloamides with unsaturated compounds”, Usp. Khim., 58:3 (1989), 417–450; Russian Chem. Reviews, 58:3 (1989), 250–271
Linking options:
https://www.mathnet.ru/eng/rcr3956https://doi.org/10.1070/RC1989v058n03ABEH003438 https://www.mathnet.ru/eng/rcr/v58/i3/p417
|
Statistics & downloads: |
Abstract page: | 114 |
|