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This article is cited in 28 scientific papers (total in 28 papers)
Modelling Reverse Osmosis
S. S. Dukhina, N. V. Churaevb, V. N. Shilova, V. M. Starovc a Institute of Colloid Chemistry and Chemistry of Water, Academy of Sciences of the Ukrainian SSR, Kiev
b Institute of Physical Chemistry, the USSR Academy of Sciences, Moscow
c Moscow Technological Institute of Food Industry
Abstract:
After a brief presentation of the principal kinetic and thermodynamic aspects of the theory of reverse osmosis, the present review examines various physicochemical mechanisms of the selectivity of membranes with respect to electrolyte solutions: the electrochemical mechanism, related to the charge of the pore surface; the dielectric exclusion of ions, due to image forces; and the structural mechanism, due to the change in the properties of water in fine hydrophilic pores. Methods for calculating the changes in the standard chemical potentials of ions on entering the membrane phase, and the effects of the Donnan exclusion of ions with allowance for the different charge of the membrane have been described. It has been concluded that it is appropriate to use charged membranes to separate electrolyte solutions at low concentrations. The problem of the transport of solutions through the fine pores of membranes has been formulated, taking account of the equilibrium distribution coefficients of the ions, their mobility, the charge of the membrane, and the phenomenon of concentration polarisation. Routes to the further development of the theory as applied to membranes of different types, different compositions, and solution concentrations have been discussed. The bibliography contains 84 references.
Citation:
S. S. Dukhin, N. V. Churaev, V. N. Shilov, V. M. Starov, “Modelling Reverse Osmosis”, Usp. Khim., 57:6 (1988), 1010–1030; Russian Chem. Reviews, 57:6 (1988), 572–584
Linking options:
https://www.mathnet.ru/eng/rcr3892https://doi.org/10.1070/RC1988v057n06ABEH003374 https://www.mathnet.ru/eng/rcr/v57/i6/p1010
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