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This article is cited in 35 scientific papers (total in 35 papers)
Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts
U. M. Dzhemilev, R. I. Khusnutdinov, G. A. Tolstikov Institute of Chemistry of the Bashkir Scientific Center, Ural Branch of the USSR, Ufa
Abstract:
The advances achieved in recent years in the synthesis of polycyclic hydrocarbons, including those containing functional substituents, from norbornadiene and its derivatives using metal complex catalysts are surveyed. The homo- and codimerisation reactions of norbornadienes with olefins, dienes, and acetylenes, involving the [2π + 2π] -, [2π + 2π + 2π] -, and [4π + 4π] -addition under the influence of transition metal complexes are examined. Data on the synthesis of norbornadiene trimers as well as the physicochemical and spectroscopic characteristics of a whole series of unique hydrocarbons are presented. The mechanisms of the reactions indicated are discussed. The bibliography includes 173 references.
Citation:
U. M. Dzhemilev, R. I. Khusnutdinov, G. A. Tolstikov, “Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts”, Usp. Khim., 56:1 (1987), 65–94; Russian Chem. Reviews, 56:1 (1987), 36–51
Linking options:
https://www.mathnet.ru/eng/rcr3772https://doi.org/10.1070/RC1987v056n01ABEH003255 https://www.mathnet.ru/eng/rcr/v56/i1/p65
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