Russian Chemical Reviews
RUS  ENG    JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PACKAGE AMSBIB  
General information
Latest issue
Archive
Impact factor
Guidelines for authors

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS



Usp. Khim.:
Year:
Volume:
Issue:
Page:
Find






Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register


Russian Chemical Reviews, 1986, Volume 55, Issue 7, Pages 622–636
DOI: https://doi.org/10.1070/RC1986v055n07ABEH003212
(Mi rcr3729)
 

This article is cited in 14 scientific papers (total in 14 papers)

The Nuclear Magnetic Resonance Spectroscopy of 15N-Labelled Cyclophosphazenes

B. Thomas, G. Grossmann

Technische Universität Dresden, Germany
English full-text Citations (14)
Abstract: The 31P NMR spectra of 15N-labelled cyclophosphazenes contain additional information compared with the unlabelled compounds, namely, apart from the spin–spin coupling constant JPN, it is also possible to obtain information, in the case of homosubstituted compounds, about the spin–spin coupling constants JPP and JNN. The 15N NMR spectra of these compounds yield the same information and in addition the chemical shift of the 15N signal. All these NMR parameters are sensitive to changes in the electronic structure of the cyclic P–N systems, which depend on the type and number of substituents and also on the ring size. Studies on labelled halides, amino-derivatives, ethers, thioethers, and alkyl-substituted derivatives of cyclic phosphazenes containing between three and six P–N structural units are examined. The NMR data are interpreted on the basis of empirical relations and also with the aid of semiempirical quantum-chemical methods.
The bibliography includes 109 references.
Russian version:
Uspekhi Khimii, 1986, Volume 55, Issue 7, Pages 1124–1146
DOI: https://doi.org/10.1070/RC1986v055n07ABEH003212
Bibliographic databases:
Document Type: Article
UDC: 541.67:546.18
Language: English
Original paper language: Russian


Citation: B. Thomas, G. Grossmann, “The Nuclear Magnetic Resonance Spectroscopy of 15N-Labelled Cyclophosphazenes”, Usp. Khim., 55:7 (1986), 1124–1146; Russian Chem. Reviews, 55:7 (1986), 622–636
Linking options:
  • https://www.mathnet.ru/eng/rcr3729
  • https://doi.org/10.1070/RC1986v055n07ABEH003212
  • https://www.mathnet.ru/eng/rcr/v55/i7/p1124
  • This publication is cited in the following 14 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Успехи химии Russian Chemical Reviews
    Statistics & downloads:
    Abstract page:131
     
      Contact us:
     Terms of Use  Registration to the website  Logotypes © Steklov Mathematical Institute RAS, 2024