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Russian Chemical Reviews, 1986, Volume 55, Issue 7, Pages 622–636
DOI: https://doi.org/10.1070/RC1986v055n07ABEH003212
(Mi rcr3729)
 

This article is cited in 14 scientific papers (total in 14 papers)

The Nuclear Magnetic Resonance Spectroscopy of 15N-Labelled Cyclophosphazenes

B. Thomas, G. Grossmann

Technische Universität Dresden, Germany
Abstract: The 31P NMR spectra of 15N-labelled cyclophosphazenes contain additional information compared with the unlabelled compounds, namely, apart from the spin–spin coupling constant JPN, it is also possible to obtain information, in the case of homosubstituted compounds, about the spin–spin coupling constants JPP and JNN. The 15N NMR spectra of these compounds yield the same information and in addition the chemical shift of the 15N signal. All these NMR parameters are sensitive to changes in the electronic structure of the cyclic P–N systems, which depend on the type and number of substituents and also on the ring size. Studies on labelled halides, amino-derivatives, ethers, thioethers, and alkyl-substituted derivatives of cyclic phosphazenes containing between three and six P–N structural units are examined. The NMR data are interpreted on the basis of empirical relations and also with the aid of semiempirical quantum-chemical methods.
The bibliography includes 109 references.
Bibliographic databases:
Document Type: Article
UDC: 541.67:546.18
Language: English
Original paper language: Russian


Citation: B. Thomas, G. Grossmann, “The Nuclear Magnetic Resonance Spectroscopy of 15N-Labelled Cyclophosphazenes”, Usp. Khim., 55:7 (1986), 1124–1146; Russian Chem. Reviews, 55:7 (1986), 622–636
Linking options:
  • https://www.mathnet.ru/eng/rcr3729
  • https://doi.org/10.1070/RC1986v055n07ABEH003212
  • https://www.mathnet.ru/eng/rcr/v55/i7/p1124
  • This publication is cited in the following 14 articles:
    1. Ibon Alkorta, José Elguero, Phosphorus, Sulfur, and Silicon and the Related Elements, 195:4 (2020), 307  crossref
    2. Ibon Alkorta, José Elguero, Alain Fruchier, Magnetic Reson in Chemistry, 57:11 (2019), 975  crossref
    3. Brian J. Cook, Samantha I. Johnson, Geoffrey M. Chambers, Werner Kaminsky, R. Morris Bullock, Chem. Commun., 55:93 (2019), 14058  crossref
    4. Zin-Min Tun, Amy J. Heston, Matthew J. Panzner, Doug A. Medvetz, Brian D. Wright, Deepa Savant, Venkat R. Dudipala, Debasish Banerjee, Peter L. Rinaldi, Wiley J. Youngs, Claire A. Tessier, Inorg. Chem., 50:18 (2011), 8937  crossref
    5. Amy J. Heston, Debasish Banerjee, Peter L. Rinaldi, Claire A. Tessier, J Inorg Organomet Polym, 17:2 (2007), 477  crossref
    6. Libor Kapička, Dalibor Dastych, Valerie Richterová, Milan Alberti, Pavel Kubáček, Magnetic Reson in Chemistry, 43:4 (2005), 294  crossref
    7. Alain Fruchier, Virginie Vicente, Ibon Alkorta, José Elguero, Magn. Reson. Chem., 43:6 (2005), 471  crossref
    8. Virginie Vicente, Alain Fruchier, Henri‐Jean Cristau, Magnetic Reson in Chemistry, 41:3 (2003), 183  crossref
    9. B. Thomas, S. Paasch, S. Steuernagel, K. Eichele, Solid State Nuclear Magnetic Resonance, 20:3-4 (2001), 108  crossref
    10. Gabino A. Carriedo, Francisco J. García Alonso, José L. García, Rodrigo J. Carbajo, Fernando López Ortiz, Eur. J. Inorg. Chem., 1999:6 (1999), 1015  crossref
    11. Christopher W. Allen, S. Davis Worley, Inorg. Chem., 38:22 (1999), 5187  crossref
    12. Silvia Paasch, Kerstin Krüger, Berthold Thomas, Solid State Nuclear Magnetic Resonance, 4:5 (1995), 267  crossref
    13. Annual Reports on NMR Spectroscopy, 25, 1993, 431  crossref
    14. S. S. Krishnamurthy, Phosphorus, Sulfur, and Silicon and the Related Elements, 41:3-4 (1989), 375  crossref
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