Abstract:
The general and theoretical aspects of the problem of hyperconjugation are examined. The factors determining the magnitude of the effect and its major role in organoelemental compounds compared with organic compounds are discussed. Various types of hyperconjugation (σ,π-, σ,σ-, and σ,p-conjugation) in the ground electronic state of organoelemental compounds of Group IV elements are considered. The bibliography includes 226 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.65+541.67+543.422+547.1'З
Language: English
Original paper language: Russian
Citation:
A. N. Egorochkin, “The Spectroscopy of Organic Compounds of Silicon Subgroup Elements and Hyperconjugation”, Usp. Khim., 53:5 (1984), 772–801; Russian Chem. Reviews, 53:5 (1984), 445–462
Linking options:
https://www.mathnet.ru/eng/rcr3552
https://doi.org/10.1070/RC1984v053n05ABEH003062
https://www.mathnet.ru/eng/rcr/v53/i5/p772
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