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This article is cited in 23 scientific papers (total in 23 papers)
Intramolecular Electronic Interactions in Phosphorus Compounds in the Light of Recent Structural Studies
R. P. Arshinova Kazan State University A. Butlerov Institute of Chemistry
Abstract:
The nature and mechanism of intramolecular electronic interactions in compounds of three- and four-coordinate phosphorus have been critically examined on the basis of a review of the results of the study of their three-dimensional structure and physical properties. The high π-acceptor power of phosphorus-containing groups, capable of stabilising conformations with the trans-orientation of the interacting orbitals of the donors (the n-orbitals of the unshared electron pairs of the heteroatoms or the π-orbitals of unsaturated systems) and the acceptors (bonds of the phosphorus atom) has been proved. The bibliography contains 193 references.
Citation:
R. P. Arshinova, “Intramolecular Electronic Interactions in Phosphorus Compounds in the Light of Recent Structural Studies”, Usp. Khim., 53:4 (1984), 595–624; Russian Chem. Reviews, 53:4 (1984), 351–368
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https://www.mathnet.ru/eng/rcr3546https://doi.org/10.1070/RC1984v053n04ABEH003056 https://www.mathnet.ru/eng/rcr/v53/i4/p595
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