Abstract:
Data concerning the influence of the electronic and steric effects of substituents as well as the structure of the connecting units on the rate and equilibrium constants for cyclisation reactions, occurring as intramolecular nucleophilic addition to a trigonal carbon atom, are examined. The general characteristics permitting the prediction of the ease of ring closure and the stability of the heterocycles are specified. The bibliography includes 166 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.614
Language: English
Original paper language: Russian
Citation:
R. Valters, “The Electronic and Steric Effects in Heterolytic Intramolecular Cyclisation Reactions”, Usp. Khim., 51:8 (1982), 1374–1397; Russian Chem. Reviews, 51:8 (1982), 788–801
Linking options:
https://www.mathnet.ru/eng/rcr3413
https://doi.org/10.1070/RC1982v051n08ABEH002911
https://www.mathnet.ru/eng/rcr/v51/i8/p1374
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