Abstract:
A systematic account is given of the literature data on the mechanism of the electrophilic halogenation of olefins. Particular attention is devoted to the experimental methods for the investigation of the structures and reactivities of the intermediate unstable adducts produced by the electrophilic addition of the halogen to the multiple bond. The relation between the mechanisms of electrophilic halogenation and other Ad reactions is discussed. Certain aspects of the stereochemistry of the addition of halogens and hypohalites to olefins are examined. The bibliography includes 192 references.
Bibliographic databases:
Document Type:
Article
UDC:
547.311
Language: English
Original paper language: Russian
Citation:
K. A. V'yunov, A. I. Ginak, “The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond”, Usp. Khim., 50:2 (1981), 273–295; Russian Chem. Reviews, 50:2 (1981), 151–163
Linking options:
https://www.mathnet.ru/eng/rcr3287
https://doi.org/10.1070/RC1981v050n02ABEH002552
https://www.mathnet.ru/eng/rcr/v50/i2/p273
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