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This article is cited in 15 scientific papers (total in 15 papers)
The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages
V. A. Zakharov, G. D. Bukatov, Yu. I. Ermakov Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Novosibirsk
Abstract:
New data on the numbers of active centres and rate constants for individual stages in the catalytic polymerisation of olefins in the presence of two-component catalysts, obtained by the method of selective radioactive inhibitors, are considered. Certain general aspects of the mechanism of the catalytic polymerisation of olefins are examined on the basis of these data as well as the results of the study of one-component organometallic catalysts and quantum-chemical investigations of the propagation reaction. The bibliography includes 102 references.
Citation:
V. A. Zakharov, G. D. Bukatov, Yu. I. Ermakov, “The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages”, Usp. Khim., 49:11 (1980), 2213–2240; Russian Chem. Reviews, 49:11 (1980), 1097–1111
Linking options:
https://www.mathnet.ru/eng/rcr3268https://doi.org/10.1070/RC1980v049n11ABEH002530 https://www.mathnet.ru/eng/rcr/v49/i11/p2213
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