Chemistry of α-Halogenonitroalkanes

Methods of preparation of α-halogenonitroalkanes and their functional derivatives are surveyed, together with the chief results obtained for the geometric parameters, electronic structure, and ultraviolet, infrared, and nuclear magnetic and quadrupole resonance spectroscopy, as well as acid–base properties. Reactions involving reduction, addition at multiple bonds, substitution of halogen atoms and the nitro-group, and interaction with diazoalkanes are analysed, and the most important mechanisms are discussed. Data are given on the toxicity, physiological activity, and practical use of these compounds. A list of 316 references is included.