Abstract:
The review is devoted to the spin-trapping method developed in recent years and used to identify short-lived radicals (mainly in liquid phase) and to investigate the mechanisms of their reactions. Unstable radicals are accepted by a spin-trapping agent with formation of a fairly stable free radical which carries information about its short-lived precursor. The EPR spectra of the resulting spin adducts can be recorded in the liquid phase and are as a rule well resolved. The properties of various spin-trapping agents are described in detail and tables of the parameters of the EPR spectra of the adducts of spin-trapping agents with the trapped radicals are presented. The application of the spin-trapping method in the study of the mechanisms of radical processes in various fields of chemistry is considered. The bibliography includes 161 references.
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Document Type:
Article
UDC:
541.14+641.15+541.514
Language: English
Original paper language: Russian
Citation:
V. E. Zubarev, V. N. Belevskii, L. T. Bugaenko, “The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes”, Usp. Khim., 48:8 (1979), 1361–1392; Russian Chem. Reviews, 48:8 (1979), 729–745
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https://www.mathnet.ru/eng/rcr3154
https://doi.org/10.1070/RC1979v048n08ABEH002407
https://www.mathnet.ru/eng/rcr/v48/i8/p1361
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