Abstract:
Data on the catalytic hydrogenation of unsaturated organic compounds in acid media are examined and discussed. A new method of catalytic hydrogenation in acid media, in which the catalyst activates hydrogen and the substrate is activated by the acid which converts it into a positively charged intermediate, is proposed. The role of catalysts as agents transferring hydride ions from molecular hydrogen to carbonium ions is considered. The bibliography includes 58 references.
Bibliographic databases:
Document Type:
Article
UDC:
542.971+542.941
Language: English
Original paper language: Russian
Citation:
M. I. Kalinkin, G. D. Kolomnikova, Z. N. Parnes, D. N. Kursanov, “Catalytic Ionic Hydrogenation”, Usp. Khim., 48:4 (1979), 612–634; Russian Chem. Reviews, 48:4 (1979), 332–342
Linking options:
https://www.mathnet.ru/eng/rcr3126
https://doi.org/10.1070/RC1979v048n04ABEH002330
https://www.mathnet.ru/eng/rcr/v48/i4/p612
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